Related resources
Search for item elsewhere
University researcher(s)
Academic department(s)
Electrochemically controlled ion exchange: Proton exchange with sodium zeolite Y
Stephenson, Michael J; Holmes, Stuart M; Dryfe, Robert A
Angew. Chem., Int. Ed. FIELD Full Journal Title:Angewandte Chemie, International Edition. 2005;44(20):3075-3078.
Access to files
Full-text and supplementary files are not available from Manchester eScholar. Use our list of Related resources to find this item elsewhere. Alternatively, request a copy from the Library's Document supply service.
Abstract
Polarized liq./liq. interfaces can be used to control ion-exchange processes. This concept is illustrated with respect to zeolites, specifically with the replacement of Na+ with H+ ions in zeolite Y. The schematic diagram shows the ion exchange in a zeolite suspended in an aq. phase with the selective extn. of Na+ ions into an org. phase. [on SciFinder (R)]
Keyword(s)
Cation exchange (electrochem. controlled cation exchange of hydrogen ion with sodium zeolite Y) ; Cyclic voltammetry (in sodium ion and hydrogen ion transfer facilitated by dibenzo[18]crown-6 at water-dichloroethane interface and electrochem. controlled ion exchange of hydrogen ion with sodium zeolite Y) ; Liquid-liquid interface (electrochem. controlled ion exchange of hydrogen ion with sodium zeolite Y) ; Zeolite NaY Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PROC (Process) (electrochem. controlled ion exchange of hydrogen ion with sodium zeolite Y) ; electrochem controlled ion exchange hydrogen ion sodium zeolite Y
Bibliographic metadata
- CAN 143:161842 72-11 Electrochemistry Journal 1433-7851 written in English. 64-19-7 (Acetic acid) Role: NUU (Other use, unclassified), USES (Uses) (chronoamperometry at dichloroethane interface with aq. acetic acid and electrochem. controlled ion exchange study of hydrogen ion with sodium zeolite Y); 12408-02-5 (Hydrogen ion); 17341-25-2 (Sodium ion) Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PROC (Process) (electrochem. controlled ion exchange of hydrogen ion with sodium zeolite Y); 14187-32-7 (Dibenzo[18]crown-6) Role: MOA (Modifier or additive use), USES (Uses) (in electrochem. controlled ion exchange of hydrogen ion with sodium zeolite Y); 227603-93-2 (Bis(triphenylphosphoranylidene)ammonium tetrakis(pentafluorophenyl)borate) Role: NUU (Other use, unclassified), USES (Uses) (in electrochem. controlled ion exchange of hydrogen ion with sodium zeolite Y); 7732-18-5 (Water) Role: NUU (Other use, unclassified), USES (Uses) (interface with dichloroethane; electrochem. controlled ion exchange of hydrogen ion with sodium zeolite Y); 107-06-2 (1,2-Dichloroethane) Role: NUU (Other use, unclassified), USES (Uses) (interface with water; electrochem. controlled ion exchange of hydrogen ion with sodium zeolite Y)